James MacDonald
James MacDonald is Molly's younger brother, 4 years old. He is in Ms. Morgan's class at daycare, and is often shy. He is sometimes annoyed by D.W..  In one episode D.W. would bug him to kiss her, thinking it would make her a princess. It is implied he has a crush on D.W., but this is never verified. Despite this, they are very good friends and enjoy being together.

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